Product ID:75080, PRANG WORKABLE FIXATIVE
MSDS Date:09/10/1997
FSC:NIIN:Submitter:D DG
Status Code:A
MSDS Number: CKVBM

SHERWIN-WILLIAMS COMPANY

101 PROSPECT AVENUE N.W.
CLEVELAND, OH 44115

Emergency Phone: 216-566-2917

Info Phone: (216) 566-2917

Cage: 56436

SHERWIN-WILLIAMS COMPANY

CLEVELAND, OH 44115 US

Telephone: (216) 566-2917

Cage: 56436

PROPANE

CAS: 74-98-6

RTECS: TX2275000

OSHA PEL 1800 MG/M3;1000 PPM

BUTANE

CAS: 106-97-8

RTECS: EJ4200000

ACGIH TLV: 1900 MG/M3;800 PPM

2-PROPANOL

CAS: 67-63-0

RTECS: NT8050000

OSHA PEL 980 MG/M3;400 PPM

ACGIH TLV: 983 MG/M3;400 PPM

2-BUTOXYETHANOL

CAS: 111-76-2

RTECS: KJ8575000

OSHA PEL 240 MG/M3;50 PPM

ACGIH TLV: 121 MG/M3;25 PPM

ACETONE

CAS: 67-64-1

RTECS: AL3150000

OSHA PEL 2400 MG/M3;1000 PPM

ACGIH TLV: 1780 MG/M3;750 PPM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

1-METHOXY-2-PROPANOL ACETATE OR 1-METHOXY-2-PROPYL ACETATE

CAS: 108-65-6

RTECS: AI8925000

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: IRRITATION OF EYES, SKIN AND
RESPIRATORY SYSTEM. MAY CAUSE NERVOUS SYSTEM DEPRESSION. EXTREME
EXPOSURE MAY RESULT IN UNCONSCIOUSNESS AND POSSIBLY DEATH. CHRONIC:
NO INGREDIENT IN THIS PRODUCT I S AN IARC, NTP OR OSHA LISTED
CARCINOGEN. PROLONGED OVEREXPOSURE TO SOLVENT INGREDIENTS LISTED IN
SECTION II (INGREDEINTS DETAIL) MAY CAUSE ADVERSE EFFECTS TO THE
LIVER , URINARY AND BLOOD FORMING SYS TEMS. REPORTS HAVE ASSOCIATED
REPEATED AND PROLONGED OVEREXPOSURE TO SOLVENTS WITH PERMANENT
BRAIN AND NERVOUS SYSTEM DAMAGE.
Explanation of Carcinogenicity:NO INGREDIENT IN THIS PRODUCT IS AN
IARC, NTP OR OSHA LISTED CARCINOGEN.
Effects of Overexposure:HEADACHE, DIZZINESS, NAUSEA, AND LOSS OF
COORDINATION ARE INDICATIONS OF EXCESSIVE EXPOSURE TO VAPORS OR
SPRAY MISTS. REDNESS AND ITCHING OR BURNING SENSATION MAY INDICATE
EYE OR EXCESSIVE SKIN EXPOSU RE.
Medical Cond Aggravated by Exposure:NONE GENERALLY RECOGNIZED.

First Aid:IF INHALED: IF AFFECTED, REMOVE FROM EXPOSURE. RESTORE
BREATHING. KEEP WARM AND QUIET. IF ON SKIN: WASH AFFECTED AREA
THROUGHLY 3 WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND
LAUNDER BEFORE R E-USE. IF IN EYES: FLUSH EYES WITH LARGE AMOUNTS
OF WATER FOR 15 MINUTES. GET MEDICAL ATTENTION. IF SWALLOWED: GET
MEDICAL ATTENTION.

Flash Point:<-17.6C, 0.F
Lower Limits:0.3
Upper Limits:13.1
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:FULL PROTECTIVE EQUIPMENT INCLUDING
SELF-CONTAINED BREATHING APPARATUS SHOULD BE USED. WATER SPRAY MAY
BE INEFFECTIVE. IF WATER IS USED, FOG NOZZLES ARE PREFERABLE. WATER
MAY BE USED TO COOL CLOSED C ONTAINERS TO PREVENT PRESSURE BUILD-UP
AND POSSIBLE AUTOIGNITION OR EXPLOSION WHEN EXPOSED TO EXTREME
HEAT.
Unusual Fire/Explosion Hazard:ISOLATE FROM HEAT, ELECTRICAL EQUIPMENT,
SPARKS, AND OPEN FLAME. CLOSE CONTAINERS MAY EXPLODE WHEN EXPOSED
TO EXTREME HEAT. APPLICATION TO HOT SURFACES REQUIRES SPECIAL
PRECAUTIONS. DURING EMERGENCY C ONDITIONS OVEREXPOSURE TO
DECOMPOSITION PRODUCTS MAY CAUSE A HEALTH HAZARD. SYMPTOM MAY NOT
BE IMMEDIATELY APPARENT.

Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND
REMOVE WITH INERT ABSORBENT.
Neutralizing Agent:NOT PROVIDED BY MANUFACTURER

Handling and Storage Precautions:KEEP AWAY FROM HEAT, SPARKS & OPEN
FLAMES. VAPORS WILL ACCUMULATE READILY & MAY IGNITE EXPLOSIVELY.
DURING USE & UNTIL ALL VAPORS ARE GONE: KEEP AREA VENTILATED-DO NOT
SMOKE-EXTINGUISH ALL FLAMES, PIL OT LIGHTS & HEATERS-TURN OFF
STOVES, ELECTRIC TOOLS & APPLIANCES & ANY OTHER SOURCES OF
IGNITION.
Other Precautions:CONSULT NFPA CODE. USE APPROVED BONDING & GROUNDING
PROCEDURES. CONTENTS UNDER PRESSURE. DO NOT PUNCTURE, INCINERATE OR
EXPOSE TO TEMPERATURES ABOVE 120F. INTENTIONAL MISUSE BY
DELIBERATELY CONCENTRAT ING AND INHALING THE CONTENTS CAN BE
HARMFUL OR FATAL.DO NOT TAKE INTERNALLY.

Respiratory Protection:IF PERSONAL EXPOSURE CANNOT BE CONTROLLED BELOW
APPLICABLE LIMITS BY VENTILATION, WEAR A PROPERLY FITTED ORGANIC
VAPOR/PARTICULATE RESPIRATOR APPROVED BY NIOSH/MSHA FOR PROTECTION
AGAINST MATERIALS IN SECTION 11.
Ventilation:LOCAL EXHAUST PREFERRED. GENERAL EXHAUST ACCEPTABLE IF THE
EXPOSURE TO MATERIALS IN SECTION 11 IS MAINTAINED BELOW APPLICABLE
EXPOSURE LIMITS.
Protective Gloves:NONE NORMALLY REQUIRED. IF PROLONGED
CONTACT/EXPOSURE:CHEMICAL RESISTANT GLOVES
Eye Protection:WEAR SAFETY SPECTACLES WITH UNPERFORATED SIDESHIELDS.
Other Protective Equipment:NOT PROVIDED BY MANUFACTURER
Work Hygienic Practices:USE ONLY WITH ADEQUATE VENTILATION. AVOID
BREATHING VAPOR AND SPRAY MIST. AVOID CONTACT WITH SKIN AND EYES.
WASH HANDS AFTER USING.
Supplemental Safety and Health
NASCO PART NUMBER: 97 14957 (X). VENTILATION: REFER TO OSHA STANDARDS
1910.94, 1910.107, 1910.108.

HCC:V3
Boiling Pt:B.P. Text:<0 -698F
Melt/Freeze Pt:M.P/F.P Text:N.A.
Vapor Density:>AIR
Volatile Org Content %:34
Spec Gravity:0.75
Evaporation Rate & Reference:FASTER THAN ETHER
Solubility in Water:N.A.
Appearance and Odor:NOT PROVIDED BY MANUFACTURER

Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Stability Condition to Avoid:NONE KNOWN.
Hazardous Decomposition Products:BY FIRE. CARBON DIOXIDE, CARBON
MONOXIDE.

Waste Disposal Methods:WASTE FROM THIS PRODUCT MAY BE HAZARDOUS AS
DEFINED UNDER THE RESOURCE CONSERVATION AN RECOVERY ACT (RCRA) 40
CFR 261. WASTE MUST BE TESTED FOR IGNITABILITY TO DETERMINE THE
APPLICABLE EPA HAZARDOUS W ASTE NUMBERS. DO NOT INCINERATE.
DEPRESSURIZE CONTAINER. DISPOSE OF IN ACCORDANCE WITH FEDERAL, STAT
E, AND LOCAL REGULATIONS REGARDING POLLUTION.

Toxicological Information:NOT PROVIDED BY MANUFACTURER

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:NOT PROVIDED BY MANUFACTURER

Transport Information:NOT PROVIDED BY MANUFACTURER

SARA Title III Information:SARA 313 (40 CFR 372.65C) SUPPLIER
NOTIFICATION: GLYCOL ETHERS, 2%.
Federal Regulatory Information:TSCA CERTIFICATION: ALL CHEMICALS IN
THIS PRODUCT ARE LISTED OR ARE EXEMPT FROM LISTING, ON THE TSCA
INVENTORY. HAZARDOUS AIR POLLUTANTS: VOLATILE HAPS POUNDS PER
GALLON: 0.11 LB/GAL; VOLATILE HAPS P OUNDS PER GALLON OF SOLIDS"
3.42 LBS/GAL; VOLATILE HAPS POUNDS PER POUND OF SOLIDS: 0.32 LB/LB.
AIR QUALITY DATA: DENSITY OF ORGANIC SOLVENT BLEND: 6.09 LBS/GAL.
PHOTOCHEMICALLY REACTIVE: NO.
State Regulatory Information:CALIFORNIA PROPOSITION 65: WARNING: THIS
PRODUCT CONTAINS CHEMICALS KNOOWN TO THE STATE OF CALIFORNIA TO
CAUSE CANCER. VOLATILE ORGANIC COMPOUNDS (FOLLOWS EPA "AS SUPPLIED"
VOC DATA SHEET): A. COATIN G DENSITY: 6.24 LB/GAL, 747 G/L; B.
TOTAL VOLATILES: 94.5% BY WT, 96.8% BY VOL; C. FEDERALLY EXEMPT
SOLVENTS: WATER, 0.0% BY WT AND VOL; ACETONE, 60.3% BY WT, 57.1% BY
VOL; D. ORGANIC VOLATILES, 34.2% BY WT, 39.7% BY VOL; E. PERCENT
NON-VOLATILE, 5.5% BY WT, 3.2 % BY VOL; VOC CONTENT 2.13 LB/GAL, 25
5 G/L; LESS EXEMPT SOLIDS, 4.96 LB/GAL, 595 G/L; SOLIDS, 66.05
LB/GAL, 7916 G/L; SOLIDS, 6.22 LB/LB, 6.22 KG/KG SOLIDS = 34.2% BY
WT.